******************************************************************* PRELIMINARY DATA: DO NOT DISTRIBUTE ******************************************************************* National Oceanic and Atmospheric Administration (NOAA) Climate Monitoring and Diagnostics Laboratory (CMDL) Carbon Cycle Greenhouse Gases (CCGG) Correspondence concerning these data should be directed to: Dr. Arlyn E. Andrews NOAA Climate Monitoring and Diagnostics Laboratory 325 Broadway, R/CMDL1 Boulder, CO 80305 U.S.A. email: Arlyn.Andrews@noaa.gov ********************* USE OF ESRL/GMD CCGG DATA ********************* These data are made freely available to the public and the scientific community in the belief that their wide dissemination will lead to greater understanding and new scientific insights. The availability of these data does not constitute publication of the data. We rely on the ethics and integrity of the user to assure that ESRL/GMD receives fair credit for our work. If the data are obtained for potential use in a publication or presentation, ESRL/GMD should be informed at the outset of the nature of this work. If the ESRL/GMD data are essential to the work, or if an important result or conclusion depends on the ESRL/GMD data, co-authorship may be appropriate. This should be discussed at an early stage in the work. Manuscripts using the ESRL/GMD data should be sent to ESRL/GMD for review before they are submitted for publication so we can insure that the quality and limitations of the data are accurately represented. *********************** RECIPROCITY AGREEMENT ********************* Use of these data implies an agreement to reciprocate. Laboratories making similar measurements agree to make their own data available to the general public and to the scientific community in an equally complete and easily accessible form. Modelers are encouraged to make available to the community, upon request, their own tools used in the interpretation of the ESRL/GMD data, namely well documented model code, transport fields, and additional information necessary for other scientists to repeat the work and to run modified versions. Model availability includes collaborative support for new users of the models. ******************************************************************** Description of Tower CO2 data file format ******************************************************************** Column 1: Year Column 2: Month Column 3: Day Column 4: Hour Column 5: Minute Column 6: Second Column 7: Sampling Level Column 8: CO2 dry air mole fraction (ppm) Column 9: Total Uncertainty estimate (ppm) Column 10: Analytical Uncertainty estimate (ppm) Column 11: Quality Flag Sampling Level: Air is sampled from 6 heights along the WLEF-TV broadcasting tower. Height above ground level is given below. 1=11m 2=30m 3=76m 4=122m 5=244m 6=396m CO2 Dry Air Mole Fraction: The CO2 abundance is given as a mole fraction with units of parts per million (ppm). This value corresponds to the number of CO2 molecules per 1 million molecules of dry air. Each data point represents a 30 sec average of data collected at 5 Hz. Uncertainty Estimates: The uncertainty estimate attempts to account for known quantifiable errors in the CO2 measurements. Uncertainty contributions include uncertainty in the calibration scale, drift in the CO2 analyzer baseline and gain between calibrations, lack of equilibration of air samples or standards, curve fitting errors, extrapolation error for samples that are outside of the calibrated range, differences in H2O content of samples and standards, and real natural variability of the CO2 abundance during the measurement period (30 sec). Calibration scale uncertainty is 0.07 ppm; analyzer drift uncertainty is typically less than 0.1 ppm; standard equilibration uncertainty, curve fitting errors, and differences in water content between samples and standards are typically each < 0.05 ppm. Sample equilibration error/atmospheric variability is the largest contribution to the total uncertainty. These terms cannot be reliably separated. Column 9 contains the Total Uncertainty estimate and this is the value that should be used in scientific analysis. Column 10 is the "analytical uncertainty estimate" and does not include sample equilibration error or atmospheric variability. Column 10 is intended for ESRL/GMD diagnostic purposes only. Quality Flag: 111= flow through licor < 50 sccm (normal flow=100sccm) 222= temporal gap in calibrations precludes reliable calculation 333= calculated CO2 mole fraction outside range of standards 900= normal operation 901= flow through licor 50-95 sccm (normal flow=100 sccm) 903= data outside of calibrated range 904= leak suspected 905= other known problem with analyzed values